Optimized Ni, Co, Mn Oxides Anchored on Graphite Plates for Highly Efficient Overall Water Splitting
نویسندگان
چکیده
Nickel, cobalt, and manganese oxides are easily obtainable non-noble metal catalysts for water splitting. However, the relationship between composition catalysts’ performance still needs systematic studies. Herein, guided by theoretical calculations, a low overpotential, prepared Mn-doped Co3O4 was deposited on graphite plates The 30% (Co2.1Mn0.9O4) required lowest overpotential oxygen evolution reaction (OER), in which Co2.1Mn0.9O4 reached 20, 30, 50 mA cm−2 overpotentials of 425, 451, 487 mV, respectively, with 90% IR compensation. Under overall water-splitting conditions, current density 30 at an 0.78 V without Charge difference analysis illustrates that doped Mn provides electrons O atoms, doping also promotes electron fluctuation Co atoms. XPS reveals Mn-doping increases chemical valence atom, atom exhibits higher than Mn3O4, is advantageous to boost form based-OOH* radical, then decrease overpotential. Considering particular simplicity growing plates, this work expected provide feasible way develop high-performance Co-Mn bimetallic oxide
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ژورنال
عنوان ژورنال: Catalysts
سال: 2023
ISSN: ['2073-4344']
DOI: https://doi.org/10.3390/catal13071031